lammps/doc/improper_ring.txt

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"LAMMPS WWW Site"_lws - "LAMMPS Documentation"_ld - "LAMMPS Commands"_lc :c
:link(lws,http://lammps.sandia.gov)
:link(ld,Manual.html)
:link(lc,Section_commands.html#comm)
:line
improper_style ring command :h3
[Syntax:]
improper_style ring :pre
[Examples:]
improper_style ring
improper_coeff 1 8000 70.5 :pre
[Description:]
The {ring} improper style uses the potential
:c,image(Eqs/improper_ring.jpg)
where K is a prefactor, theta is the angle formed by the atoms
specified by (i,j,k,l) indices and theta0 its equilibrium value.
If the 4 atoms in an improper quadruplet (listed in the data file read
by the "read_data"_read_data.html command) are ordered i,j,k,l then
theta_{ijl} is the angle between atoms i,j and l, theta_{ijk} is the
angle between atoms i,j and k, theta_{kjl} is the angle between atoms
j,k, and l.
The "ring" improper style implements the improper potential introduced
by Destree et al., in Equation (9) of "(Destree)"_#Destree. This
potential does not affect small amplitude vibrations but is used in an
ad-hoc way to prevent the onset of accidentially large amplitude
fluctuations leading to the occurrence of a planar conformation of the
three bonds i-j, j-k and j-l, an intermediate conformation toward the
chiral inversion of a methine carbon. In the "Impropers" section of
data file four atoms: i, j, k and l are specified with i,j and l lying
on the backbone of the chain and k specifying the chirality of j.
The following coefficients must be defined for each improper type via
the "improper_coeff"_improper_coeff.html command as in the example
above, or in the data file or restart files read by the
"read_data"_read_data.html or "read_restart"_read_restart.html
commands:
K (energy/radian^2)
theta0 (degrees) :ul
theta0 is specified in degrees, but LAMMPS converts it to radians
internally; hence the units of K are in energy/radian^2.
:line
[Restrictions:]
This improper style can only be used if LAMMPS was built with the
USER-MISC package. See the "Making LAMMPS"_Section_start.html#start_3
section for more info on packages.
[Related commands:]
"improper_coeff"_improper_coeff.html
:link(Destree)
[(Destree)] M. Destree, F. Laupretre, A. Lyulin, and J.-P. Ryckaert,
J Chem Phys, 112, 9632 (2000).